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Seven well-known personalities, all with differing faiths and beliefs, put on backpacks and walking boots and, on foot and by road, set out to cover sections of the Sultans Trail - a modern-day, 2,200km pilgrimage across Eastern Europe, which starts in Vienna and ends in the historic city of Istanbul.

With only 15 days to complete their pilgrimage, the group begin their adventure in the capital of Serbia, Belgrade. From here, they make their way to Bulgaria, travelling over the mountainous Balkans before arriving in Istanbul. But will this journey of a lifetime change the way they think about themselves and their beliefs?

Journalist Adrian Chiles, former politician Edwina Currie, Olympian Fatima Whitbread, comedian Dom Joly, actor Pauline McLynn, broadcaster Mim Shaikh and television presenter Amar Latif live as modern-day pilgrims, staying in basic hotels and often sleeping in shared rooms.

Formed just over ten years ago, the Sultans Trail retraces an ancient path taken by the Ottoman armies from late medieval times as they looked to expand their empire into Europe. From their base in Istanbul, armies made it to the city of Vienna twice before being repelled. Now, this former route of war has been turned into a path of peace, designed to promote tolerance between people of all faiths and none.

In this first episode, the seven pilgrims arrive in Belgrade, Serbia, and find out for the first time who they are sharing their pilgrim adventure with. Leaving the city behind, they head into the countryside and away from the hustle and bustle. Relying on the Sultans Trail app to help guide them across Europe, Adrian, a converted Catholic, and Mim, a practising Muslim, are the first to plot their way as they look for the fortified Manasija monastery hidden in the hills. As they progress through the Serbian countryside, Amar, who has been blind since the age of 18, leads the pilgrims in the ancient tradition of scrumping.

After a 5km hike, they make it to the monastery, which was fortified to protect it from the Ottoman armies. Adrian leads the group in exploring the 15th-century Orthodox Christian church. Inside, Edwina, a non-practising Orthodox Jew, and Mim discuss the existence of God. Meanwhile, outside on the ramparts of the fortress, Dom, an atheist, takes Amar, raised a Muslim, to the very top of the battlements with some nerve-racking moments!

They move on and, with the sun setting, the pilgrims arrive at their overnight accommodation, a simple woodland hostel, and, in line with pilgrim tradition, bed down in shared rooms. In the morning, it becomes clear the boys have had a restless night thanks to Dom and Adrian snoring. Mim takes himself off to pray in a field near the hostel before breakfast, where Pauline, an atheist, tells the group about her upbringing as an Irish Catholic. Before they set off, the pilgrims collect their first pilgrim stamp, a record of their journey along the trail.

Later that day, the group arrive in the city of Nis, where Dom and Mim explore a 16th-century mosque built during the reign of Sultan Suleiman, after whom the pilgrimage trail is named. Edwina takes Amar and Pauline to a memorial of a more recent conflict, the Crveni Krust concentration camp, a Second World War Nazi camp that held people of Jewish, Romani and Serbian origin. Here, they witness the horrors of religious and cultural persecution. After a challenging day, the group discuss the difficulties with faith and religion in the face of conflict.

The next day, the pilgrims head back into rural Serbia, where Fatima, a Christian, takes the lead with the app, but the pilgrims end up lost and separated in a forest as they lose the trail, much to new hiker Mim’s annoyance. After reuniting, the pilgrims pick up the trail again and it brings them to The Church of the Virgin Mary on a special day in the Orthodox Christian calendar, the birth of the Holy Virgin Mary.

The Saint’s day is celebrated with a Slava, a day-long festival that comprises of a service and meal. The pilgrims settle into the service but it is not long before Dom decides to leave. Adrian however finds the service comforting, and after it is completed, the group are invited to join the locals’ celebration meal at the priest’s top table. The experience of seeing this local community come together in the name of faith resonates with Amar, while for Mim, being surrounded by people embracing their faith gives him a new outlook on his own.